Using Unbleached Bagasse Fibers for Fabricating Magnetic Paper

Document Type : Research Paper

Authors

1 Assistant Professor, Department of Wood and Paper Science and Technology, Natural Resources Faculty, University of Tehran, Karaj, I.R. Iran

2 M.Sc Graduate, Department of Wood and Paper Science and Technology, Natural Resources Faculty, University of Tehran, Karaj, I.R. Iran

3 M.Sc Graduate, Wood and Paper Engineering Faculty, Gorgan University of Agricultural Sciences and Natural Resources, KaraGorgan, I.R. Iran

Abstract

Magnetic lignocellulosic fibers have good potential in applications such as information storage, security papers, electromagnetic shielding and etc. In this study unbleached bagasse fibers were used to fabricate magnetic paper by chemical co-precipitation method. Lumen loading and precipitation of magnetic nanoparticles on the surface of fibers were carried out by in situ synthesis. Then the formation of magnetite and hematite nanoparticles during synthesis process was demonstrated by patterns of X-ray diffraction (XRD). Micrographs of scanning electron microscopy (SEM) indicated well the nanoparticles deposition on the fiber surfaces. Degree of loading increased with increasing temperature up to 60 ̊C and iron content of suspension up to 6mmol. The magnetic particles deposited on the fiber surfaces had detrimental effects on the tensile strength of the magnetic papers. Measuring the magnetic properties with vibrating sample magnetometer (VSM) demonstrated the superparamagnetic behavior of fabricated papers. Magnetization at saturation (Ms) of the papers was increased by increase in loading degree.

Keywords


[1]. Dong, C., Song, D., Patterson, T., Ragauskas, A., and Deng, Y. (2008). Energy saving in papermaking through filler addition. Industrial & Engineering Chemistry Research, 47:8430–8435.
[2]. Shen, J., Song, Zh., Qian, X., and Ni., Y. (2011). A Review on use of fillers in cellulosic paper for functional applications. Industrial & Engineering Chemistry Research, 50:661–666.
[3]. Marchessault, R.H., Rioux, P., Raymond, L. (1992). Magnetic cellulose fibres and paper: preparation, processing and properties. Polymer, 33: 4024–4028.
[4]. Small, A.C. and Johnston, J.H. (2009). Novel hybrid materials of magnetic nanoparticles and cellulose fibers. Journal of Colloid and Interface Science, 331:122-126.
[5]. Carrazana-Garcia, J.A., Lopez-Quintela, M.A., and Rivas-Rey, J. (1997). Characterization of ferrite particles synthesized in presence of cellulose fibers,  Colloids and Surfaces A: Physicochemal and Engineering Aspects, 121:61-66.
[6]. Zakaria S., Ong, B.H., and Van de Ven, T.G.M. (2004). Lumen loading magnetic paper Ι: flocculation. Colloids and  Surfaces A: Physicochemal Engineering Aspects, 251:1-4.
[7]. Ainun, Z.M., Sarani, Z., Roslinda, Sh., and Mustaffa, H.A. (2010). Cationic starch as a dry strength agent in magnetic papermaking. Sains Malaysiana, 39(2):239-242.
[8]. Mashkour, M., Tajvidi, M., Kimura, T., Kimura, F., and Ebrahimi, Gh. (2011). Fabricating unidirectional magnetic papers using permanent magnets to align magnetic nanoparticles covered natural cellulose fibers. BioResources, 6(4):4731-4738.
[9]. Chia, C.H., Zakaria S., Nguyen K.L., and Abdullah M. (2008). Utilisation of unbleached kenaf fibers for the preparation of magnetic paper. Industrial Crops and Products, 28:333-339.
[10]. Chia, C.H., Zakaria S., Nguyen K.L., Dang, V.Q., and Duong, T.D. (2009). Characterization of magnetic paper using Fourier transform infrared spectroscopy. Materials Chemistry and Physics, 113:768-772.
[11]. Petlicki, J., and Van de Ven, T.G.M. (1994). Kinetics of lumen loading. Journal of Pulp and Paper Science, 20:375-382.
[12]. Bhattacharya, I.N., Pradhan, J.K., Gochhayat, P.K., and Das, S.C. (2002). Factors controling precipitation of finer size alumina trihydrate. International Journal of Mineral Processing, 65:109-124.