Evaluation of Contact Angle and Leach Resistance of Beech Wood Treated with Nano-Zinc Oxide

Document Type : Research Paper

Authors

1 M.Sc. Student, Wood and Paper Science and Technology, Islamic Azad University, Chalous Branch, Chalous, I.R. Iran

2 Instructor, Wood and Paper Science and Technology, Islamic Azad University, Chalous branch, Chalous, I.R. Iran

Abstract

The objective of this research is characterizing the effect of Nano-Zinc oxide (nano-ZnO) dispersions on leach resistance and contact angle of beech wood (Fagus orientalis Lipsky). The Beech wood was cut into standard dimension, and oven dried after treating with nano-Zno solution, based on immersion method. Three treating nano-Zno solution levels: (o, 20000 and 40000 ppm), and two thermal treating levels: (60 and 120ºC) were selected. After conditioning, leaching tests were performed and contact angle of samples after 1 and 10 seconds were measured. The results showed that by increasing of the nano material concentration and the temperature, the contact angle increased. In tenth second, the minimum and maximum angles were 53.30º and 90.07º which observed for untreated sample and for 40000 ppm concentration and 120ºC temperatures, respectively. Improving on contact angle represents the significant reduction in wettability property of surface in treated wood. Results of leaching test implied that effect of increment of nano-zno concentration was negligible, while the temperature increasing resulted in nano-ZnO stabilization

Keywords


[1]. Freeman, H., and Mclntyre, R. (2008). Comprehensive review of copper-based wood preservatives. Forest Products Journal, (11): 6–27.
[2]. Heidman, G., Noordermeer, J.W.M., Datta, R.N. and Baarle, B.V. (2007). Various ways to reduce zinc oxide levels in S-SBR rubber compounds. World Polymer Congress, 245-246(1):657-667
[3]. Azadfar, D., Ali Ahmad Korori, S., Haddadchi, G., Akbarynia, and S.M., Galali, G.A. (2005 .(Study of peroxidase and alpha-amylase activities in different growth stages of beech (Fagus orientalis Lipsky). Pajouhesh & Sazandgi, 62: 25-31.
[4]. Clausen, C.A. (2007). Nanotechnology: implications for the wood preservation industry. International Research Group on Wood Protection, Stockholm, Sweden, IRG/WP/07-30415.15p.
[5]. Gholamiyan, H., Tarmian, A., DoostHosseini, K., and Azadfallah, M. )2011(. The effect of clear paints, nanozycofil and nanozycosil on water absorption and contact angle of poplar wood. Iranian Journal of Wood and Paper Industries, 2(1): 18-22.
[6]. Khranovsky, V. , Ekblad, T., Yakimova, R., and Hultman, L. (2012). Surface morphology effects on the light-controlled wettability of ZnO nanostructures, Applied Surface Science, 258(20): 8146-8152.
[7]. Clausen, C.A., Yang, V.W., Arango, R.A., and Green, III F. (2010). Feasibility of Nanozinc Oxide as a Wood Preservative. Proceeding American Wood Protection Assocciation, 105, 255–260.
[8]. Kartal, S.N, Green, lll F., and Clausen, C.A. (2009). Do the unique properties of nanometals affect leachability or efficacy against fungi and termites International Biodeterioration & Biodegradation, 63:490-495.
[9]. Clausen, C.A., Green, F., and Kartal, N. (2010). Weatherability and leach resistance of wood impregnated with Nano-Zinc oxide. Nanoscale Research Letter, 5:1464–1467.
[10]. Cooper, A., and Ung, Y. (2008). Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives. International Research Groupon Wood Protection, Stockholm, Sweden, IRG/WP/08-50258.14p.
[11]. Matsunaga, H., Kiguchi, M., and Evans, P. (2007). Micro-distribution of metals in wood treated with a nano-copper wood preservative. International Research Group on Wood Protection. Document No. IRG/WP/07-40360. 10p.
[12]. Leach, R.M., and Zhang, J. )2005(. Micronized Wood Preservative Formulation. World Patent, 2005104841, 26.
[13]. Chen, R., Chen, D., and Li, H. )2006(. Wood preservative containing copper and ammonium compounds. Chinese Patent, 1883899, 10.
[14]. Hosseini, H. (2011). Evaluation of natural durability and dimensional stability of beech wood treated with Nano-Zinc oxide against white rot. M Sc. Thesis, Azad University of Chaloos branch, 120 pp.
[15]. Goss, K.,andSchwarzenbach, R. (2003). Rules of thumb for assessing equilibrium partitioning of organic compounds: successes and pitfalls. Journal of Chemical Education, 80(4): 450-455.
[16]. Xu, S., and Wang, Z.L. (2011). One-dimensional ZnO nanostructures: solution growth and functional properties. Nano Research, 4(11): 1013-1098.