Effects of Pre-Extraction of Hemicelluloses on the Pulping and Papermaking Properties of Bagasse

Document Type : Research Paper

Authors

1 M.Sc., Faculty of Natural Resources, University of Tehran, Karaj, I.R.Iran

2 Associate Professor, Faculty of Natural Resources, University of Tehran, Karaj, I.R.Iran

3 Assistant Professor, Faculty of Natural Resources, University of Tehran, Karaj, I.R.Iran

Abstract

Biomass pretreatment plays a crucial role in a lignocelluloses feedstock-based biorefinery for
processing of three major output streams (cellulose, hemicelluloses and lignin) into chemicals
and biofuels. Biomass pretreatment includes processing of lignocellulosic material under
aqueous, dilute acid or alkaline media to obtain a cellulosic fraction, which in then produce
added-value products. In this study, the effect of pre-extraction on alkaline pulping (soda)
and papermaking properties of Bagasse was investigated. Samples of sugar cane bagasse
were hydrolysed by auto hydrolysis with hot-water. Results showed that pre-extraction
optimum conditions were 30 min, 135OC and 10 min 170OC, resulted in extraction yield and
holocellulose removal of 86% and 11%, respectively. Also, the pulping optimum conditions
were alkali charge 17%, 165 OC for 1h. The results indicated that for unbleachable pulp
production the pulping yield from the extracted bagasse is higher than the unextracted bagasse
but the bleached pulp from unextracted bagasse have higher yield compared to the extracted
bagasse. Pulp strength properties such as the tensile index and the burst index were found to be
lower when pre-extraction was applied.

Keywords


[1]. Cheng, H., Huaiyn, Z., Shiyu, F., and Lucian, L. A. (2010). Alkali extraction of hemicelluloses
from depithed corn stover and effected on Soda-AQ pulping. Bioresurces, 11(1): 196-206.
[2]. Carvalheiro, F., Luis, C., and Francisco, M. (2008). Hemicellulose biorefineries: a review on
biomass pretreatment. Journal of Scientific & Industrial Research, (67): 849- 864.
[3]. Al-Dajani, W., and Tschirne, U. (2008). Pre-extraction of hemicelluloses and subsequent Kraft
pulping. Part I. Alkaline extraction. TAPPI Journal, 7(6): 3–8.
[4]. Lei, Y., Liu, S., Li, J. and Sun, R. (2010). Effect of hot-water extraction on alkaline pulping of
bagasse. Biotechnolgy Advances, (10): 10-16.
[5]. Hamzeh, Y., Abyaz, A., Mirfatahi, M., and Abdokhani, A. (2011). Application of surfactants
for improving soda pulping of bagasse. Journal of Chemistry and Chemistry Engineering of Iran,
29(2): 85-90.
[6]. Rossell, C.E.V., Pradella J.G.C., Gomez E.O. and Squina Centro de Cienciae, F.M. (2006).
Physical conditioning unit of the sugarcane biomass feedstock: Sugarcane bagasse and sugarcane
trash-PPDP1, Workshop on Hydrolysis Route for Cellulosic Ethanol from Sugarcane, Centro de
Ciência e Tecnologia do Bioetanol, February 10-11th, 2009 - Campinas - SP, Brazil, p 30.
[7]. Youn, W, H., Edwin, A., and Ciegler, A. (1983). Chemical and physical properties of sugarcane
bagasse irradiated with y (gamma) Rays. Journal of Agricultural and Food Chemistry, (31): 34-
38.
[8]. Walford, SN. (2008). Sugarcane Bagasse: How Easy Is It To Measure Its Constituents?,
Proceedings. Congress of the South African Sugar Technologists Association, (81): 266-273.
[9]. Yichao, L. Shijie, L. Jiang, L., and Runcang, S. (2010). Effect of hot-water extraction on alkaline
pulping of bagasse. Biotechnology Advances, (10): 10-16.
[10]. Gamez, S., Gonzalez-Cabriales, J., Alberto Ramırez , J., Garrote, G., and Vazquez, M. (2006).
Study of the hydrolysis of sugar cane bagasse using phosphoric acid. Journal of Food Engineering,
(74): 78–88.
[11]. Lu, H., Hu, R., Ward, A., E.Amidon, T., Liang, B., and Liu, S. (2011). Hot-water xtraction and
its effect on soda pulping of aspen woodchips. Biomass & Bioenergy, (1): 10-16.
[12]. Lavarack, B.P., Gri(nb), G.J., and Rodmanc, D. (2002). The acid hydrolysis of sugarcane
bagasse hemicellulose to produce xylose, arabinose, glucose and other products. Biomass and
Bioenergy, (23): 367–380.